Celebrity Couples Who Met On Set, And Now They’re In Love

36. Brad Pitt and Angelina Jolie

Movie: Mr. and Mrs. Smith
Location: Los Angeles, California
Year: 2005

Of all the Hollywood stars on this list, few shine as brightly as Brad Pitt and Angelina Jolie. And few have as widely-known a love story as the two of them. Their tale could go on for pages, but we’ll keep it simple. Pitt and Jolie met on the set of their thriller, Mr. and Mrs. Smith.

Not only were the two on-screen love interests, they kindled a romance on the set as well. Pitt left actress Jennifer Aniston for Jolie, who gave up acting for activism and recently starred in the Disney movie Maleficent. Though the pair have since split, they were together for a long time—twelve years in total.