Celebrity Couples Who Met On Set, And Now They’re In Love

82. Leighton Meester and Sebastian Stan

Movie: Gossip Girl
Location: New York City, New York
Year: 2007

Sebastian Stan and Leighton Meester met on the set of Gossip Girl in 2007. While it’s hard to think of the tough-as-nails Marvel ex-assassin being on a show like Gossip Girl, he was, and it was where he met his ex-girlfriend. The two began dating in 2008, and they broke up in 2010.

Rumors of their romance swirled in 2008 when people noticed that they were very touchy-feely at an industry dinner. Stan would later call Meester the most “interesting” and “sophisticated” person he knew. Though they were thought to be engaged, that was fake, and the two parted ways two years after dating.