Celebrity Couples Who Met On Set, And Now They’re In Love

94. Angelina Jolie and Billy Bob Thornton

Movie: Pushing Tin
Location: Toronto, Canada
Year: 1999

The relationship between Angelina Jolie and Billy Bob Thornton was something else (remember when they wore vials of each other’s blood around their necks?). The pair met on the set of Pushing Tin, a 1999 comedy-drama that made $8.4 million at the box office.

The two met and fell in love on the set of the movie. Jolie had split from her ex-husband, Jonny Lee Miller, a couple of years earlier. After Jolie and Thornton realized they had an instant connection, they began dating and eloped to Las Vegas the next year. They were married from 2000 until 2002. Though it didn’t work out, Jolie said she is still “good friends” with the actor.